/***
     * 构建httpPost请求
     * @param url 第三方接口地址
     * @param jsonObject 所需传的参数
     * @param multipartFile 文件流
     * @return
     */
    public static String sendHttpPostRequest(String url,JSONObject jsonObject, MultipartFile multipartFile) throws  Exception{
        HttpClient httpClient = new DefaultHttpClient();
        HttpPost httpPost = new HttpPost(url);
        MultipartEntityBuilder entityBuilder = MultipartEntityBuilder.create();
        entityBuilder.setMode(HttpMultipartMode.BROWSER_COMPATIBLE);
        entityBuilder.setCharset(Charset.forName("utf-8"));
        /***
         * 这里需要将multiPartFile 转成File文件
         */
        InputStream inputStream = multipartFile.getInputStream();
        String path = System.getProperty("java.io.tmpdir");
        FileOutputStream bufferedWriter = new FileOutputStream(path+"/"+multipartFile.getOriginalFilename());
        byte[] arr = new byte[2048];
        while((inputStream.read(arr,0,arr.length)) != -1){
            bufferedWriter.write(arr);
        }
        File file = new File(path+"/"+multipartFile.getOriginalFilename());
        entityBuilder.addTextBody("callbackUrl",jsonObject.getString("callbackUrl"));
        entityBuilder.addTextBody("serialNo",jsonObject.getString("serialNo"));
        entityBuilder.addPart("voiceFilePath",new FileBody(file,multipartFile.getOriginalFilename(),multipartFile.getContentType(),"utf-8"));
        httpPost.setEntity(entityBuilder.build());
        HttpResponse httpResponse = httpClient.execute(httpPost);
        String responseJson = EntityUtils.toString(httpResponse.getEntity());
        return responseJson;
    }

另附：
java发送post请求，使用multipart/form-data的方式传递参数，可实现服务器间文件上传功能

/**
     * 测试上传图片
     * 
     */
    public static void testUploadImage(){
        String url = "http://xxxtest/xxx/xxx";
        //文件路径，文件存在，不存在的话需要先下载下来
        String fileName = "文件路径";
        Map<String, String> textMap = new HashMap<String, String>();
        //可以设置多个input的name，value
        textMap.put("name", "testname");
        textMap.put("type", "2");
        //设置file的name，路径
        Map<String, String> fileMap = new HashMap<String, String>();
        fileMap.put("upfile", fileName);
        String contentType = "";//image/png
        String ret = formUpload(url, textMap, fileMap,contentType);
        System.out.println(ret);
        //{"status":"0","message":"add succeed","baking_url":"group1\/M00\/00\/A8\/CgACJ1Zo-LuAN207AAQA3nlGY5k151.png"}
    }

    /**
     * 上传图片
     * @param urlStr
     * @param textMap
     * @param fileMap
     * @param contentType 没有传入文件类型默认采用application/octet-stream
     * contentType非空采用filename匹配默认的图片类型
     * @return 返回response数据
     */
    @SuppressWarnings("rawtypes")
    public static String formUpload(String urlStr, Map<String, String> textMap,
            Map<String, String> fileMap,String contentType) {
        String res = "";
        HttpURLConnection conn = null;
        // boundary就是request头和上传文件内容的分隔符
        String BOUNDARY = "---------------------------123821742118716"; 
        try {
            URL url = new URL(urlStr);
            conn = (HttpURLConnection) url.openConnection();
            conn.setConnectTimeout(5000);
            conn.setReadTimeout(30000);
            conn.setDoOutput(true);
            conn.setDoInput(true);
            conn.setUseCaches(false);
            conn.setRequestMethod("POST");
            conn.setRequestProperty("Connection", "Keep-Alive");
            // conn.setRequestProperty("User-Agent","Mozilla/5.0 (Windows; U; Windows NT 6.1; zh-CN; rv:1.9.2.6)");
            conn.setRequestProperty("Content-Type","multipart/form-data; boundary=" + BOUNDARY);
            OutputStream out = new DataOutputStream(conn.getOutputStream());
            // text
            if (textMap != null) {
                StringBuffer strBuf = new StringBuffer();
                Iterator iter = textMap.entrySet().iterator();
                while (iter.hasNext()) {
                    Map.Entry entry = (Map.Entry) iter.next();
                    String inputName = (String) entry.getKey();
                    String inputValue = (String) entry.getValue();
                    if (inputValue == null) {
                        continue;
                    }
                    strBuf.append("\r\n").append("--").append(BOUNDARY).append("\r\n");
                    strBuf.append("Content-Disposition: form-data; name=\"" + inputName + "\"\r\n\r\n");
                    strBuf.append(inputValue);
                }
                out.write(strBuf.toString().getBytes());
            }
            // file
            if (fileMap != null) {
                Iterator iter = fileMap.entrySet().iterator();
                while (iter.hasNext()) {
                    Map.Entry entry = (Map.Entry) iter.next();
                    String inputName = (String) entry.getKey();
                    String inputValue = (String) entry.getValue();
                    if (inputValue == null) {
                        continue;
                    }
                    File file = new File(inputValue);
                    String filename = file.getName();
                    
                    //没有传入文件类型，同时根据文件获取不到类型，默认采用application/octet-stream
                    contentType = new MimetypesFileTypeMap().getContentType(file);
                    //contentType非空采用filename匹配默认的图片类型
                    if(!"".equals(contentType)){
                        if (filename.endsWith(".png")) {
                            contentType = "image/png"; 
                        }else if (filename.endsWith(".jpg") || filename.endsWith(".jpeg") || filename.endsWith(".jpe")) {
                            contentType = "image/jpeg";
                        }else if (filename.endsWith(".gif")) {
                            contentType = "image/gif";
                        }else if (filename.endsWith(".ico")) {
                            contentType = "image/image/x-icon";
                        }
                    }
                    if (contentType == null || "".equals(contentType)) {
                        contentType = "application/octet-stream";
                    }
                    StringBuffer strBuf = new StringBuffer();
                    strBuf.append("\r\n").append("--").append(BOUNDARY).append("\r\n");
                    strBuf.append("Content-Disposition: form-data; name=\"" + inputName + "\"; filename=\"" + filename + "\"\r\n");
                    strBuf.append("Content-Type:" + contentType + "\r\n\r\n");
                    out.write(strBuf.toString().getBytes());
                    DataInputStream in = new DataInputStream(new FileInputStream(file));
                    int bytes = 0;
                    byte[] bufferOut = new byte[1024];
                    while ((bytes = in.read(bufferOut)) != -1) {
                        out.write(bufferOut, 0, bytes);
                    }
                    in.close();
                }
            }
            byte[] endData = ("\r\n--" + BOUNDARY + "--\r\n").getBytes();
            out.write(endData);
            out.flush();
            out.close();
            // 读取返回数据
            StringBuffer strBuf = new StringBuffer();
            BufferedReader reader = new BufferedReader(new InputStreamReader(conn.getInputStream()));
            String line = null;
            while ((line = reader.readLine()) != null) {
                strBuf.append(line).append("\n");
            }
            res = strBuf.toString();
            reader.close();
            reader = null;
        } catch (Exception e) {
            System.out.println("发送POST请求出错。" + urlStr);
            e.printStackTrace();
        } finally {
            if (conn != null) {
                conn.disconnect();
                conn = null;
            }
        }
        return res;
    }

本人做了一个调python接口给其传wav格式的文件和mp3格式文件，
第一种方式都可以，第二种方式wav格式文件有问题，不知那里情况，希望了解的笔友给出建议。